Cu–Mo Differential Mineralization Mechanism of the Dabate Polymetallic Deposit in Western Tianshan,NW China: Evidence from Geology,Fluid Inclusions,and Oxygen Isotope Systematics     

Rui Cao  Shengchao Yan  Bin Chen  Keke Sun  Qinglin Zhang  Haodong Gu 《Resource Geology》2020,70(1):50-69

Classic porphyry Cu–Mo deposits are mostly characterized by close temporal and spatial relationships between Cu and Mo mineralization. The northern Dabate Cu–Mo deposit is a newly discovered porphyry Cu–Mo polymetallic deposit in western Tianshan, northwest China. The Cu mineralization postdates the Mo mineralization and is located in shallower levels in the deposit, which is different from most classic porphyry Cu–Mo deposits. Detailed field investigations, together with microthermometry, laser Raman spectroscopy, and O‐isotope studies of fluid inclusions, were conducted to investigate the origin and evolution of ore‐forming fluids from the main Mo to main Cu stage of mineralization in the deposit. The results show that the ore‐forming fluids of the main Mo stage belonged to an NaCl + H₂O system of medium to high temperatures (280–310°C) and low salinities (2–4 wt% NaCl equivalent (eq.)), whereas that of the main Cu stage belonged to an F‐rich NaCl + CO₂ + H₂O system of medium to high temperatures (230–260°C) and medium to low salinities (4–10 wt% NaCl eq.). The δ¹⁸O values of the ore‐forming fluids decrease from 3.7–7.8‰ in the main Mo stage to ?7.5 to ?2.9‰ in the main Cu stage. These data indicate that the separation of Cu and Mo was closely related to a large‐scale vapor–brine separation of the early ore‐forming fluids, which produced the Mo‐bearing and Cu‐bearing fluids. Subsequently, the relatively reducing (CH₄‐rich) Mo‐bearing, ore‐forming fluids, dominantly of magmatic origin, caused mineralization in the rhyolite porphyry due to fluid boiling, whereas the relatively oxidizing (CO₂‐rich) Cu‐bearing, ore‐forming fluids mixed with meteoric water and precipitated chalcopyrite within the crushed zone at the contact between rhyolite porphyry and wall rock. We suggest that the separation of Cu and Mo in the deposit may be attributed to differences in the chemical properties of Cu and Mo, large‐scale vapor–brine separation of early ore‐forming fluids, and changes in oxygen fugacity.  相似文献   

早渐新世钙质超微化石演变与营养盐及二氧化碳关系     

马瑞罡  杨海长  金晓波  赵钊  张功成  刘传联 《海洋学报(英文版)》2020,39(10):70-80

南海北部早渐新世发生明显的营养供给和二氧化碳浓度的变化，相关地质记录为研究颗石藻的生理机制提供了理想的自然实验室。在本研究中，我们建立了一个新的颗石藻群落演化的指标，定义为E*比值。该比值由富营养属种和中等-贫营养属种的相对丰度计算而得（E^*=e/(e+c)×100，e代表富营养属种，c代表中等-贫营养属种）。其中富营养属种包括小Reticulofenestra， Reticulofenestra lockeri组，Reticulofenestra bisecta组和Coccolithus pelagicus组，而中等-贫营养属种包括Cyclicargolithus spp.。E^*指标与早渐新世营养盐指标具有较强的相关性，但在不同二氧化碳浓度的条件下表现不同的公变趋势。将群落组合与已发表的二氧化碳浓度数据对比，我们提出颗石藻可能在二氧化碳持续降低的环境下改变其对碳源和营养盐的利用方式，指示颗石藻的碳浓缩机制可能开始于早渐新世。  相似文献   

短蛸对不同生物饵料利用的比较     

赵捷杰  陈四清  常青  徐大凤  李凤辉  张鹏飞 《海洋科学》2020,44(9):83-90

为比较短蛸（Octopus ocellatus）对不同生物饵料的利用效果，以南美白对虾、肉球近方蟹、菲律宾蛤仔和玉筋鱼四种饵料进行了饲喂实验。结果表明：1）肉球近方蟹组短蛸增重率显著高于其他各组（P<0.05），南美白对虾组脏体比显著高于玉筋鱼组（P<0.05），各饵料组肝体比无显著差异；2）南美白对虾组和肉球近方蟹组短蛸肌肉的蛋白质含量显著高于菲律宾蛤仔组和玉筋鱼组（P<0.05），肉球近方蟹组脂肪含量显著高于其余各组（P<0.05），玉筋鱼组灰分含量显著低于其他各组（P<0.05）；3）南美白对虾组短蛸肝胰腺谷丙转氨酶活性显著高于其余各组（P<0.05），肉球近方蟹组谷草转氨酶活性显著高于其余各组（P<0.05），玉筋鱼组谷氨酸脱氢酶活性显著低于其余各组（P<0.05），菲律宾蛤仔组酸性磷酸酶活性显著高于其余各组（P<0.05），玉筋鱼组胃蛋白酶活性显著高于其他各组（P<0.05）。综上，投喂肉球近方蟹可以显著提高短蛸的增重率；不同饵料对短蛸肌肉的蛋白质、脂肪和灰分含量有影响，对其肝胰腺功能和胃蛋白酶活性也有显著影响。  相似文献   

羧乙基壳聚糖蒙脱石吸附养殖水体中Cu²⁺的应用     

李俭平  周忻宇  代婧炜  沈庆洲 《海洋科学》2020,44(2):120-130

为了寻求性能良好、环保吸附剂,用于去除养殖水体中重金属Cu~(2+),作者利用蒙脱石负载羧乙基壳聚糖制备成复合吸附剂,并利用IR、SEM、XRD等手段分析其表面性能,将其用于处理Cu~(2+)溶液,考察了环境因子对其吸附性能的影响,并从吸附动力学和吸附热力学角度分析吸附剂对Cu~(2+)的吸附机理,最后考察其再生利用效果。结果表明:羧乙基壳聚糖成功进入到蒙脱石层间;在羧乙基壳聚糖与蒙脱石质量比为1︰25、40℃恒温水浴搅拌60min、pH=6.0、最佳投加量为4.0g/L、处理浓度不超过30 mg/L Cu~(2+)溶液时,复合吸附剂对Cu~(2+)去除率可以达到96.23%,将其用于淡水养殖鱼塘水体中, Cu~(2+)去除后可达到《渔业水质标准》规定;吸附剂对Cu~(2+)吸附热力学实验结果表明,符合Langmuir模型,反应过程为自发、吸热反应;吸附动力学结果表明该吸附符合准二级动力学方程,反应属于化学吸附;再生实验中NaOH的再生效果优于HCl。  相似文献   

我国生物海岸修复现状及展望     

张小霞  陈新平  米硕  龚泽林  林鹏智 《海洋通报》2020,39(1):1-11

介绍了我国生物海岸的分布现状,总结出以柽柳为代表的灌木群落、以芦苇为代表的草本群落、以红树林为代表的常绿灌木与乔木群落以及珊瑚礁是我国海岸带四类典型生物群落。生物海岸的生态、旅游、渔牧和科研价值极高,但从20世纪50年代起,由于对生物海岸的价值认识不足,我国生物海岸被大量破坏,主要破坏原因可归纳为:1)土地功能转换式开发引起的红树林和草本岸线破坏;2)过度采挖及环境恶化引起的珊瑚礁破坏;3)土壤盐碱化引起的柽柳群落退化。从20世纪80年代至今,一系列海岸带保护与生态修复的举措陆续实施,减缓了我国海岸带生态加速破坏的态势,较好地保护和修复了我国生物海岸,其中最重要的举措包括:1)设立生物海岸湿地公园和自然保护区;2)建立健全生物海岸保护相关法律体系;3)开展典型生物海岸相关研究与修复技术探索;4)推进并实施"十三五"海洋规划中三大海洋重点工程。为了解我国海岸带生态修复的现状,于2017-2018年期间,分别在山东日照、潍坊,上海,广东汕头、汕尾以及徐闻进行了实地调研和测量,调研结果表明:在政策支持下,调研地区的生物海岸得到了很好的保护和修复,推进我国海岸带生态修复步入快速发展阶段。基于调研成果,指出我国在海岸带生态修复中应特别重视的一些问题。  相似文献   

2014年夏季长江流域持续性低温的大尺度环流异常          下载免费PDF全文

杜雪婷  陆尔  赵玮 《大气科学学报》2021,44(5):795-803

采用中国地面站气温逐日观测资料、NOAA全球逐日海表温度资料,及NCEP/NCAR的全球日均再分析资料,研究了2014年持续性低温的三维结构及大尺度环流异常。结果表明,2014年的低温异常,除了在陆地上区域性地出现在长江流域,还以大尺度带状的形式、从陆地延伸到海洋上。这种带状异常不只出现在近地面,在大气各层（925～500 hPa）都能看到。分析指出,大气中的这个低温带主要由高纬大气环流异常造成。在位势高度场上,最重要的异常出现在高纬60°N,有呈带状的位势高度正距平,它引导（距平意义上的）偏北气流从正北和东北偏东方向侵入,在其南侧形成一带状的偏低温区。大气各层均呈现出这种在高纬有位势高度正距平、相应地在稍南的低纬（40°N）有位势高度负距平、两者之间为低温区的分布特征。从低层往上,这种配置型式整体表现出由南往北的倾斜,其垂直剖面表现为距平意义上的、大尺度、类似于锋面的倾斜结构。文中用简单的概念模型对此进行理解,认为这种结构是由大气动力异常和热力异常相互影响、共同作用而形成的。  相似文献   

西太平洋暖池对夏季华东海面日最大风速变化的影响          下载免费PDF全文

韩雪  徐经纬  刘杨珂 《大气科学学报》2021,44(5):727-736

利用1979—2018年ERA Interim地面10 m风场、位势高度场、温度场和风场,Hadley中心HadISST再分析海温资料,采用SVD分析、合成分析等方法,研究了夏季（6—8月）西太平洋暖池关键海域海表面温度（Sea Surface Temperature,简称SST）对华东海域夏季10 m日最大风速变化的影响关系。SVD分析结果表明,夏季华东近海风速变化与菲律宾以东海域SST有明显负相关,第一模态左、右空间向量的时间系数相关达0.58,通过了置信度为95%的显著性检验。当西太平洋暖池SST正异常时,暖池海域SST增高,西北太平洋副热带高压（以下简称副高）加强,副高脊线北进（西北太平洋副高脊线纬度位置与暖池SST相关系数达到0.46,通过置信度为95%显著性检验）。此时华东近海正处于副高控制,近海下沉运动增强,大气温度垂直剖面有普遍增温现象,10 m风场有偏北风异常,海面风速减小约占40 a平均风速的约30%;当暖池SST负异常时,副高东撤南退,华东近海冷空气活动加强,温度垂直剖面存在显著降温现象,华东近海风速增加占40 a平均风速的20%以上。本研究进一步说明了暖池SST异常是一个有效的预报因子,可用于华东近海海面风速预测预报。  相似文献   

The geothermal formation mechanism in the Gonghe Basin: Discussion and analysis from the geological background     

《China Geology》2018,1(3):331-345

The Gonghe Basin, a Cenozoic down-warped basin, is located in the northeastern part of the Qinghai-Xizang (Tibetan) Plateau, and spread over important nodes of the transfer of multiple blocks in the central orogenic belt in the NWW direction. It is also called “Qin Kun Fork” and “Gonghe Gap”. The basin has a high heat flow value and obvious thermal anomaly. The geothermal resources are mainly hot dry rock and underground hot water. In recent years, the mechanism of geothermal formation within the basin has been controversial. On the basis of understanding the knowledge of predecessors, this paper proposes the geothermal formation mechanism of the “heat source–heat transfer–heat reservoir and caprock–thermal system” of the Gonghe Basin from the perspective of a geological background through data integration-integrated research-expert, discussion-graph, compilation-field verification and other processes: (1) Heat source: geophysical exploration and radioisotope calculations show that the heat source of heat in the basin has both the contribution of mantle and the participation of the earth’s crust, but mainly the contribution of the deep mantle. (2) Heat transfer: The petrological properties of the basin and the exposed structure position of the surface hot springs show that one transfer mode is the material of the mantle source upwells and invades from the bottom, directly injecting heat; the other is that the deep fault conducts the deep heat of the basin to the middle and lower parts of the earth’s crust, then the secondary fracture transfers the heat to the shallow part. (3) Heat reservoir and caprock: First, the convective strip-shaped heat reservoir exposed by the hot springs on the peripheral fault zone of the basin; second, the underlying hot dry rock layered heat reservoir and the upper new generation heat reservoir and caprock in the basin revealed by drilling data. (4) Thermal system: Based on the characteristics of the “heat source-heat transfer-heat reservoir and caprock”, it is preliminarily believed that the Gonghe Basin belongs to the non-magmatic heat source hydrothermal geothermal system (type II2₁) and the dry heat geothermal system (type II2₂). Its favorable structural position and special geological evolutionary history have given birth to a unique environment for the formation of the geothermal system. There may be a cumulative effect of heat accumulation in the eastern part of the basin, which is expected to become a favorable exploration area for hot dry rocks.  相似文献   

Multi-factor sensitivity analysis on the stability of submarine hydrate-bearing slope     

《China Geology》2018,1(3):367-373

There are many factors affecting the instability of the submarine hydrate-bearing slope (SHBS), and the interaction with hydrate is very complicated. In this paper, the mechanical mechanism of the static liquefaction and instability of submarine slope caused by the dissociation of natural gas hydrate (NGH) resulting in the rapid increase of pore pressure of gas hydrate-bearing sediments (GHBS) and the decrease of effective stress are analyzed based on the time series and type of SHBS. Then, taking the typical submarine slope in the northern South China Sea as an example, four important factors affecting the stability of SHBS are selected, such as the degree of hydrate dissociation, the depth of hydrate burial, the thickness of hydrate, and the depth of seawater. According to the principle of orthogonal method, 25 orthogonal test schemes with 4 factors and 5 levels are designed and the safety factors of submarine slope stability of each scheme are calculated by using the strength reduction finite element method. By means of the orthogonal design range analysis and the variance analysis, sensitivity of influential factors on stability of SHBS are obtained. The results show that the degree of hydrate dissociation is the most sensitive, followed by hydrate burial depth, the thickness of hydrate and the depth of seawater. Finally, the concept of gas hydrate critical burial depth is put forward according to the influence law of gas hydrate burial depth, and the numerical simulation for specific submarine slope is carried out, which indicates the existence of critical burial depth.  相似文献   

淮河流域(河南段)连续性暴雨天气分型及环流背景          下载免费PDF全文

梁钰  王君  吴璐 《气象与环境科学》2019,42(2):48-54

利用19812016年68月河南省淮河流域64个国家自动观测站逐日2020时日降水量资料、常规高空探测和地面观测资料等对淮河流域连续性暴雨时间分布特征、影响系统等进行分析和天气分型,结果表明:1)36年淮河流域共发生45次连续性暴雨,2000年的最多,19982008年是高发期,近10年较少,年出现次数无明显减少趋势,存在2~4年和4~6年两个周期;7月连续性暴雨次数最多,6月的最少,旬分布呈正态分布;最长连续时间5天,连续2天的最多。2)影响系统主要有切变线和高低空急流,高空急流在方向转换的过程中,降水有24h左右的减弱期,低空急流有明显的日变化特征,夜间加强,白天减弱。3)连续性暴雨按照500hPa影响系统,分为低槽型、副高边缘型、西北低涡型三类。4)以不同类型的3次典型连续性暴雨为例,从大尺度环流背景、高度距平场、水汽输送、高低空急流等方面探讨了连续性暴雨的维持成因,3次连续性暴雨的发生与异常的500hPa大气环流、高低空急流、切变线和持续偏强的水汽输送等有关。  相似文献